Undersanding Solution Gas-Oil Ratio
The Solution Gas-Oil Ratio which is also known as gas solubility (Rs) is defined as the number of standard cubic feet of gas which will dissolve in one stock-tank barrel of crude oil at certain pressure and temperature. This value is constant at pressures greater than the bubble point pressure as there is no free gas in the reservoir (undersaturated oil reservoir) and below the bubble point pressure, the solution gas-oil ratio decreases as the pressure decreases. The dissolved gas consists mostly of the light hydrocarbons (Methane, Ethane, Propane, and Butane) and some inorganic impurities (Nitrogen, Carbon Dioxide, Hydrogen Sulfide, etc.). The typical Oilfield unit of Rs is standard cubic feet of gas per stock tank barrel of oil (scf/stb).
Main Factors Affecting Rs
- Pressure (P): The solubility of gas in liquid is directly proportional to the pressure of the gas in contact with liquid.
- Temperature (T): The solubility of gas in liquid decreases as temperature increases. This is because higher temperatures provide more energy for gas molecules to escape from the liquid.
- Oil gravity (API): The solubility of gas in liquid is directly proportional to the API gravity of the oil in contact with gas; the higher the API gravity, the higher the solubilty.
- Gas specific gravity (γg): The solubility of gas in liquid is directly proportional to the specific gravity of the gas in contact with liquid. Gases with higher specific gravity (heavier gases) tend to be more soluble in oil.
Key Points
PVT laboratories can provide actual solution gas-oil ratios from direct measurement, and empirical correlations can be made based on PVT laboratory data. Although most of the empirical correlations presented to estimate the solubility of gases in oil use affecting parameters listed above, some empirical relationships have been developed based on other additional parameters. It must be noted that at known pressure and temperatures below bubble point pressure, oil-gas solubility can be calculated precisly using material balance. Below are some common correlations developed for estimating oil-gas solubility.